The words Sango from the Explorers passed on were "summon Rayquaza". Friede uses this clue to locate the island where the Explorers' hideout is located. Liko, Roy, Friede and Randou head to this island, but are met with a trap set by Spinel! Will Liko and the others be able to stop the Explorers' Plan for Capturing Rayquaza?

Only 30 boxes of the famous treat "Sea Digdaman" are sold every day, and you have to stand in line for them too. However, as a thank you for helping the store manager, Liko and Roy are given some even without having to stand in line. A certain person from the Explorers was standing in line for the treats as well, though... and as they're on their way back to the Brave Asagi, Roy notices a letter of challenge that has been stuck to Hogator's back...?!

The Rising Volt Tacklers are visiting a beach in the Paldea region. Liko and Roy are having a great time playing with the local sea Pokémon, but trouble suddenly arises when Hogator gets washed out to sea! The day ends up getting saved by Irukaman, the Hero of the Sea! Roy is amazed at how cool Irukaman is... but just then, someone is lurking nearby, planning to catch Irukaman's supposedly never-before-seen transformation scene on camera...?

Dot's mother Blanca visits the Brave Asagi. It appears she's there to pick up Dot, who's only been on the ship on a trial basis... Liko and Roy want to make Dot stay, so they decide to ask her how she truly feels about all of this. It's time to reveal the never-before-told story of how Dot joined the Rising Volt Tacklers!

Liko and Nyahoja are engaged in battle practice with Roy and Hogator... or at least that was the idea, but then Nyahoja accidentally ends up injuring Liko! Liko ensures Nyahoja it's not to blame for what happened, but it seems like Nyahoja still feels conflicted. It ultimately ends up running away from the Brave Asagi, heading for the breeding house where it was born and raised?!

Liko, Roy and Dot are shopping in Tetsuron Town, a town famous for its industrial products, when Dot gets separated from the other two. While going around on her own, Dot encounters a Kanuchan, a Pokémon said to pound iron scraps together to make a hammer. And it seems the Kanuchan is interested in a certain something Dot got......?

Molly is performing a medical checkup on the Pokémon while the Brave Asagi is docked after a storm, but as Liko is taking Mibrim there for its checkup, Mibrim senses someone. Believe it or not, it turns out to be a single Wakkanezumi that has gotten onto the ship. Wakkanezumi normally operate in pairs, so it's strange for one to be alone like this. Maybe something serious has happened?!

The Rising Volt Tacklers answer a request from an archeologist acquaintance of Friede's to move some rocks at an archeological dig and head for the dig site. However, they have difficulties getting started with the work, as ferocious Waruvile and Waruvial seem to be interfering. Liko, Roy and Friede set off to investigate inside the ruins to get to the bottom of this.

During a livestream, a listener asks Gurumin for help, explaining that there's a tag battle tournament coming up, but her partner Perfuton refuses to team up with anyone. Gurumin asks Liko, Roy and Kuwassu for help. It appears the Perfuton is actually in love...?

The Rising Volt Tacklers have finally run out of operating funds... so Friede and Cap decide to accept a request to search for a lost Anokusa in order to make some money! Liko is working on a presentation about "her ideal bond" for class and decides to help search for the Anokusa with Roy so she can observe Friede and Cap in action, however...?!

Liko's grandmother Diana has decided to disembark from the Brave Asagi, and Liko and Roy start working with their companions and Pokémon in secret on a farewell party for her! Meanwhile, the battle against the Black Rayquaza has made Amethio fully realize his own inadequacies. Aiming high, he approaches Hamber with a certain request, but...

The Rising Volt Tacklers thought the case was closed after they got their feelings across to the Laplace from the Six Heroes... but then the Black Rayquaza they had been chasing down suddenly appeared high up in the sky! Roy yells a challenge to a battle at it... but then Amethio from the Explorers barges in! Liko and the others are in deep trouble after Rayquaza gets enraged from being attacked... But suddenly Terapagos' body starts shining?!

Laplace has finally emerged from the mist, just like Friede planned it. Could this shining Pokémon that resonates with Terapagos actually be one of Lucius' Six Heroes...? However, the Laplace and its Pokémon companions end up attacking the Brave Asagi! Is it time for a battle on the sea between the Rising Volt Tacklers and the Pokémon group?!

Liko and the others hear of a shining Laplace and decide to search the sea for it, thinking it might be the one that's part of the Six Heroes...!

Hogator thought it was time to train... but then it suddenly slipped due to a mysterious purple liquid being splattered around on the battlefield?! Roy decides to investigate where it came from together with Hogator. In the meantime, Liko hears a mysterious clanging sound...?! Just what is going on on the Brave Asagi?

The information they got from Tepen sends Liko, Roy, Friede and Orio to a monster ball factory in the Galar region. The factory is run by the monster ball craftsman Karna, who has a deep interest in unusual balls! Orio hits it off with Karna since they're both craftsmen, however... Karna then makes a certain suggestion...?!

When Roy's Ancient Poké Ball is stolen, the Rising Volt Tacklers track down the thief!

A visit to the Wild Area turns into a curry-making adventure for the Rising Volt Tacklers!

A curious Liko tries to keep up with Terapagos as it explores the Brave Olivine.

Working separately, Amethio and Hamber both set out to steal Terapagos from Liko.

Finally meeting up with her grandma, Liko learns the identity of the pendant Pokémon.

Faced with an enraged Galarian Moltres, Liko comes up with a different kind of strategy.

Inside Galar Mine, Liko and the others find a Pokémon that doesn't seem happy to see them!

After rescuing a wild Hatenna, Liko contemplates her own feelings—and makes a new friend!

Liko, Roy and their Pokémon receive some red-hot training from Gym Leader Kabu!

A stop at the Battle Café in Motostoke brings back painful memories for Murdock.

Friede tells the Rising Volt Tacklers the story of how he and Captain Pikachu first met.

Fuecoco and Wattrel aren't getting along, so Roy sets up some teamwork training!

Officially a trainer, Dot teams up with Quaxly to help take back Liko’s stolen pendant!

Liko has gone missing, so Dot calls on a celebrity connection for help!

As Friede tracks suspicious activity, Roy comes up with some special training for Wattrel.

While the Brave Olivine has its computer system rebooted, it’s picnic time for the crew!

After learning the story of the Ancient Adventurer, Liko is faced with a decision.

Searching for Arboliva, Liko, Roy and Mollie discover a forest devastated by wildfire.

Liko and Roy arrive in Artazon, but gym leader Brassius is in an artistic slump!

Back in Paldea, the time has come for Liko to part ways with the Rising Volt Tacklers.

While the rest of the crew goes shopping, Liko ramps up her efforts to befriend Dot.

Liko and Roy learn a thing or two about Pokémon battles from Friede and Captain Pikachu!

A Rayquaza suddenly emerges from Roy’s Ancient Poké Ball, leaving everyone with questions!

After Roy sneaks onto the Brave Olivine, he and Fuecoco get their chance to shine!

As Liko settles in on the Brave Olivine, the Fuecoco who lives on the ship goes missing!

Liko, Friede and the other Rising Volt Tacklers set out to rescue Sprigatito.

Friede, Captain Pikachu and the Rising Volt Tacklers step up to help protect Liko.

Liko arrives at Indigo Academy and meets her partner Pokémon, Sprigatito.